Product ID:N-4761 LT GREEN TREE MARKING PAINT
MSDS Date:05/08/1991
FSC:8010
NIIN:01-273-3769
MSDS Number: BKMHY

NILES CHEMICAL PAINT

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 47%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ALKYD RESIN

Fraction By Weight: 18%

COBALT (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: < 1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE (SARA III)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: < 1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

PROPRIETARY INGREDIENTS

Fraction By Weight: BALANCE

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: < 1%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

4.43 LB/GL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: SEVERE IRRITATION, LACRIMATION.
REDNESS, BLURRED VISION, VISUAL DISTURBANCES, EYE BURNS. SKIN:
ABSORPTION IN TOXIC AMOUNTS. INHALATION: NASAL AND/OR RESPIRATORY
IRRITATION. CNS DEPRESSION (DIZZIN ESS, DROWSINESS, WEAKNESS,
FATIGUE, CONFUSION), NAUSEA, HEADACHE, VERTIGO, POSSIBLE
UNCONSCIOUSNESS, ASPHYXIATION.
Effects of Overexposure:INGEST: GASTROINTESTINAL IRRITATION, ABDOMINAL
PAIN, NAUSEA, VOMITING, DIARRHEA, BLINDNESS AND DEATH. CHRONIC:
HEMOLYSIS, HEMOGLOBINURIA.
Medical Cond Aggravated by Exposure:TARGET ORGANS: SKIN, EYES,
RESPIRATORY SYSTEM, CNS, GI TRACT, LIVER, KIDNEYS, LYMPHOID SYSTEM,
BLOOD

First Aid:INHALE: MOVE TO FRESH AIR. ARTIFICIAL RESPIRATION IF NEEDED.
MEDICAL AID AS SOON AS POSSIBLE. SKIN: WASH WITH SOAP AND WATER.
EYE: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MIN,
LIFTING L IDS. GET IMMED MEDICAL AID. INGEST: DRINK 1 OR 2 GLASSES
OF WATER. DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY. TREAT SYMPTOMATICALLY.

Flash Point Method:TCC
Flash Point:102F,39C
Lower Limits:0.8
Upper Limits:36.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE IN POSITIVE
PRESSURE MODE & FULL PROTECT CLOTHES. USE WATER TO COOL CLOSED
CONTAINERS/ PREVENT PRESS BUILD-UP/AUTO-IGNITE/EXPLOSION.
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLOSED, AWAY FROM
IGNITE SOURCES. HOT SURFACE APPLIC NEEDS SPECIAL PRECAUTION.
OVEREXPOSE TO DECOMP MAY CAUSE UNAPPARENT HEALTH HAZ, SEE DR.

Spill Release Procedures:ELIMINATE ALL IGNITE SOURCES. MINIMIZE THE
BREATHING OF VAPORS AND AVOID SKIN CONTACT. ABSORB AND/OR DIKE TO
PREVENT FURTHER MOVEMENT. RECLAIM INTO RECOVERY OR SALVAGE DRUMS OR
TANK TRUCK FOR DISPOSAL .

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMPERATURE
AREAS OR NEAR FIRE OR OPEN FLAME. KEEP CONTAINERS CLOSED WHEN NOT
IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.

Respiratory Protection:WEAR (TYPE TC-23C-75) PROPERLY FITTED HALF-MASK
OR FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER
APPLICATION UNLESS AIR MONITORING VAPOR/MIST LEVELS ARE BELOW
APPLICABLE LIMITS.
Ventilation:SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP THE AIR
CONCENTRATION BELOW CURRENT OSHA PEL OR ACGIH TLV LIMITS.
Protective Gloves:CHEM RESISTANT (NITRILE OR VITON) GLOVES
Eye Protection:CHEM GOGGLES, SAFETY GLASSES, FACESHIELD
Other Protective Equipment:CHEMICAL RESISTANT (NITRILE OR VITON)
CLOTHING AS NEEDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
RESTROOM.
Supplemental Safety and Health
REMOVE DECOMPOSITION PRODUCTS FORMED DURING WELDING OR FLAME CUTTING OF
SURFACES COATED WITH THIS PRODUCT. FOR BAKING FINISHES-VENT VAPORS
EMITTED ON HEATING. REMOVE CONTAMINATED CLOTHES AND WASH BEFO RE
REUSE. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH THIS PRODUCT.

HCC:F4
Boiling Pt:B.P. Text:146 TO 330F
Decomp Temp:Decomp Text:NE
Vapor Density:> THAN AIR
Viscosity:40-45 SZ#2
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, ODOR OF SOLVENTS
Percent Volatiles by Volume:69.59

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FROM DROPPING.
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.
Conditions to Avoid Polymerization:HIGH TEMPERATURES, SHOCK FROM
DROPPING.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. EPA HAZARDOUS WASTE CODE:
D-001 (IGNITABLE)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.